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- 7 - Earth Systems and Environmental Sciences
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- Is this case study continued from a case study submitted in 2014?
- No
1. Summary of the impact
The development of accurate exploration models for geological resources is a critical economic consideration for the mineral industry. Durham University led research by Selby has delivered impact worth 100s of millions of US Dollars to the global mineral (e.g., copper, gold, molybdenum) industry (e.g., Canada, Chile, Greece, Brazil). This impact has arisen through the development and application of rhenium-osmium (Re-Os) isotope geochemistry to determine the age and source of mineralisation. This Durham-delivered geochemical tool enables the development of more accurate geological models for industry and also permits improved reserve estimates, reduced exploration budgets and minimises the environmental impacts of global exploration.
2. Underpinning research
The underpinning research carried out by Selby (Professor, appointed 2005) and his research group at Durham University (from appointment to present) addresses longstanding academic (industry-related) issues concerning the development of subsurface Earth resources. Specifically, exactly when, how and where do resources, such as copper, molybdenum and gold form in rocks? Analytical and technological advances, developed by Durham-led research, have permitted the use of previously challenging geochemical methods to help answer old, but critically important geological questions – what is the geological age of the metal enrichment in the Earth’s crust? Selby, his research group and international collaborations (10 PhD students, 4 post-doctoral researchers, and researchers worldwide: cf. [R1-6]; and references therein (Section 3) have pioneered, refined and applied the application of rhenium-osmium (Re-Os) radioisotope methods to sulphide minerals. The referred to underpinning research (Section 3) has demonstrated independently that the rhenium decay constant is accurately and precisely determined, critical knowledge underpinning Re-Os geochronology [R1]. It has also developed a mineral purification protocol permitting the isolation of ultrafine molybdenite (50-100 µm grain size) in rocks, thus extending the application to more mineralisation styles [R2]. Papers R3-6 demonstrate the critical application of establishing the timeframe of geological events within various mineral systems, with a particular focus to porphyry type systems, which are explicit to this case study. Overall, the research culminates in developing an understanding of the optimal use of molybdenite for both accurate and precise Re-Os geochronology in ore systems. [R1 - 6].
This case deals specifically with the outcomes and impacts of molybdenite Re-Os geochronology for the mineral industry. Molybdenite (a molybdenum disulphide, MoS2) is enriched in Re on formation and not Os. With time, the rhenium isotope 187Re decays to form the osmium isotope 187Os, and thus permits the age of the molybdenite formation to be determined by isotopic analysis. Selby and co-workers [e.g., R1-6 and therein] have demonstrated the unique ability of the Re-Os molybdenite geochronometer to yield a more accurate and precise determination of the absolute timing of metal precipitation compared to other radioisotope methods (e.g., Ar-Ar, Rb-Sr etc) and this precise determination allows companies to operate and search in new ways.
Selby’s research has permitted a greatly enhanced understanding of the best Re-Os analytical protocols, age accuracy and precision, and elemental behaviour in rocks and minerals. This has allowed the determination of Re-Os ages for sulphide minerals (e.g., molybdenite) [R1-6], and the ability to use Os isotope compositions (e.g., pyrite, chalcopyrite) to identify the source of ore metals [references therein of R1-6]. Moreover, this has improved our understanding of genetic models for mineral systems [e.g., R1, 2, 4, 6 and references therein].
In terms of impact, the outcome yields critically necessary data required for exploration programmes [Section 4]. Ultimately Selby’s research has shown that the Re-Os system, and specifically that related to dates obtained from molybdenite, can be applied much more widely than previously thought [ R2, 4-6]. This has placed Durham at the forefront in the use of this novel research tool both academically and through industry as a fundamental exploration tool. Selby’s Re-Os research leadership is recognised internationally through published literature that he has authored or co-authored since 2001. He is the recipient of the William Smith Fund (2009 from the Geological Society of London, and has been honoured as an elected Fellow of the Geological Society of America (2018) for excellence in contributions to applied and economic aspects of the science. He was also awarded the 2019 Impact and Engagement Technical and Commercial prize, by Durham University.
3. References to the research
[bracketed values in bold are the number of citations, Google Scholar]
[R1] Selby, D., Creaser, R.A., Stein, H. J., Markey, R. J., Hannah, J. L., 2007. Assessment of the 187Re decay constant accuracy and precision: Cross calibration of the 187Re-187Os molybdenite and U-Pb zircon chronometers. Geochimica et Cosmochimica Acta, 71, 1999-2013. [125] DOI: 10.1016/j.gca.2007.01.008
[R2] Lawley, C.J.M., and Selby, D. 2012. Re-Os Geochronology of Quartz Enclosed Ultra-fine Molybdenite: Implications for Ore Geochronology, Economic Geology, v. 107, p. 1499-1505 . [25] DOI: 10.2113/econgeo.107.7.1499
[R3] Li., J, Bi, S., Selby, D., Chen, L., Vasconcelos, P., Thiede, D., Zhou, M., Zhao, X., Li., Z., Qiu, H., 2012. Giant Mesozoic gold provinces related to the destruction of the North China craton, Earth and Planetary Science Letters, v. 349-350, 26-37. [183] DOI: 10.1016/j.epsl.2012.06.058
[R4] Lawley, C.J., Selby, D., Imber, J., 2013. Re-Os Molybdenite, Pyrite, and Chalcopyrite Geochronology, Lupa Goldfield, Southwestern Tanzania: Tracing Metallogenic Time Scales at Midcrustal Shear Zones Hosting Orogenic Au Deposits. Economic Geology, v. 108, p. 1591-1613. [39] DOI: 10.2113/econgeo.107.7.1499
[R5] Buret, Y., von Quadt, A, Heinrich, C., Selby, D. Walle, M., 2016 . From a long lived upper crustal magma chamber to rapid porphyry copper emplacement: Reading the geochemistry of zircon crystals at Bajo de la Alumbrera (NW Argentina). Earth and Planetary Science Letters, v. 450, p. 120-131, [61] DOI: 10.1016/j.epsl.2016.06.017
[R6] Li, Y., Selby, D., Condon, D., Tapster, S., 2017. Cyclic magmatic-hydrothermal evolution in porphyry systems: High-precision U-Pb and Re-Os geochronology constraints from the Tibetan Qulong porphyry Cu-Mo deposit. Economic Geology, v. 112, 1419-1440. [33] DOI: 10.5382/econgeo.2017.4515
All papers are published in international peer reviewed journals.
Paper R1: A critical and highly cited paper than provides an assessment of the accuracy and precision of the decay constant of the rhenium. Critical for the application of the rhenium-osmium geochronometer, which is fundamental for the geochronology of molybdenite.
Papers R2 – 6: Discusses analytical advancements to further the applications of rhenium-osmium molybdenite geochronology and our understanding of mineral resource formation processes.
Paper R1: Led to the award of the William Smith Fund (2009) to Selby from the Geological Society of London. This award is made for research excellence in contributions to applied and economic aspects of the science.
Papers R2 – 6: This body of work is recognised by Selby election as a Fellow of the GSA, noting his career to date in being one the leading geochemists.
Papers R1 – 6: Were recognised in 2019 award for Impact and Engagement Technical and Commercial prize by Durham University.
Papers R1 – 6: The underpinning research has also been presented through several invited keynote conference presentations at major international conferences, e.g., AGU Fall Meeting 2011 ; GSA 2011, 2012, 2013, 2015, 2019; EGU 2013; Goldschmidt 2015; Mineral Deposits Studies Group 2011-16; IGC 2016; Pardee Symposium to Honor Arthur Holmes (1890-1965) for Contributions to Geochronology, Plate Tectonics, & the Origin of Granite.
4. Details of the impact
A metallogenic belt is typically formed by multiple geological events that have led to the Earth’s crust being endowed in metals that are associated with different formation mechanisms as well as ages. As such, for economic exploration, it is critical to establish the geological age of the metal (e.g., copper, gold, molybdenum) enrichment in the Earth’s crust that a company is targeting. Herein lies the power of the application of the Re-Os molybdenite chronometer based on Durham-led research [e.g., R1 – 6] and why companies such as Rio Tinto and MMG, as part of their exploration program want to establish the chronology of the mineral enrichment targeted in their exploration programmes . Commissioned through focused industry-based (Rio Tinto, MMG, Eldorado, Sun Metals – see below) research projects at Durham, Re-Os molybdenite ages (hereafter referred to as Durham-led Research - DLR) have provided critical data to evaluate exploration models. This allows mineral companies to devise accurate resource estimates and exploration programmes and save exploration expenditure and thereby reduce any industry-related environmental impact. Although due to confidentiality exact figures cannot be given, the total impact claimed here is worth hundreds of millions of US dollars.
In the cases discussed below, the impact has occurred since August 2013 and is on-going, as is the nature of impact with mineral exploration. Companies will not divulge the specific details of their explorations to maintain their competitive market position, but they have provided testimony that falls within the REF period.
*Rio Tinto and MMG Impact cases [E1, 2]
The DLR has provided Rio Tinto and MMG data that has permitted reassessment of mining activities and exploration in the REF period, respectively. The DLR has resulted in plans to increase the life of mine operations at one of the World’s major copper producers for another 20 years. This yielded a revenue of hundreds of millions of US dollars.
Both Rio Tinto and MMG are major explorers for porphyry-related copper reserves (supply ~75 % of the world’s copper) that typically also contain significant reserves of molybdenum and gold. Porphyry deposits are a major geological manifestation of where the Earth’s crust has been repeatedly intruded by small porphyry plutons that also channel metal-rich fluids, resulting in a local enrichment of metals (e.g., copper), with the younger events often overprinting the older events [R2 – 6 and industry-led research at Durham ], or occurred spatially close together (< a few kms) or at deeper crustal levels. Over the last decade, it has been shown that the youngest magmatic-hydrothermal event is typically the major carrier of the economic resource. As such, knowing the age of the sequence of the magmatic-hydrothermal events [R2 - 6] is of paramount importance in determining the likely economic value during preliminary exploration.
DLR Outcome 1 – During the REF period the MMG case highlights how the Re-Os molybdenite ages obtained by DLR have specifically aided in providing the understanding that the economic mineralisation occurred in a very short time interval (0.5 millions of years), and is only specifically related to one intrusion event (the youngest), although the prospect geology includes igneous activity that spans nine million years. This has benefited MMG by permitting the company to focus their exploration accordingly. The company state that, whilst it is difficult to put an absolute financial figure on the impact, direct savings in terms of drilling (USD 100,000 per drill hole – exploration at this scale involves 100+ drill holes) and time (e.g., mapping, assay analysis, geophysics, etc) had enormous impacts. Specifically: ‘ Constraining the timing / geological formation of metal enrichment is fundamental to not only the scientific understanding of how economic concentration of copper and molybdenum (Cu-Mo) form, but also to develop financially effective exploration programme and deposit models. The geological dating of the Mo bearing mineral molybdenite by the Re-Os radioisotope tool is the most accurate and precise methodology to achieve this, with the laboratory at Durham University led by David Selby being world leading in its development and application.’ Principal Exploration Geologist, MMG Las Bambas **[E1] .
DLR Outcome 2 - During the REF period, one case from Rio Tinto, at Escondida, Chile, highlights how DLR has permitted the company to restructure its mine site to access and maximise exploitation of the greatest endowment of copper in the region. In a development costing hundreds of millions of dollars, DLR has permitted the company to expand their exploration to locate the most economic concentration of copper. This will ultimately lead to revenues far exceeding the initial development expenditure for the company. The mine restructuring will result in an increase in the lifespan of the mining at Escondida yielding enhanced employment security for hundreds of Chileans and revenue for Chili. The Principal Geologist, at Rio Tinto states: ‘For Rio Tinto, the recognition of the value Re-Os molybdenite geochronology that is provided by Prof Selby at Durham University has changed the way in which we explore for resources over the last five years’ [E2].
Eldorado Gold Corporation Impact cases [E3]
For Eldorado Gold, DLR has aided in steering the company’s exploration program which runs in to CAD10sMillion.
DLR Outcome 3 - During the REF period, in Brazil, DLR identified an age that is genetically associated with the copper and not gold mineralisation. As Eldorado Gold is a gold-focused company, this allowed the company to re-evaluate their exploration program, which in this case, involved leaving the prospect area that, although economic for copper, was not economic for gold. This was an important decision as halting exploration resulted in savings that would have run into several millions of Canadian dollars (CAD). Chief Geoscientist, Eldorado Gold states : ‘The Re-Os molybdenite date allude to the fact that the molybdenite was genetically associated with the Cu-Mo system and not the gold-bearing IRGS system. This was critical in guiding our exploration in the region because as a gold-focused company the IRGS were the most attractive target and thus allowed the company to pull back on the Cu-Mo exploration. As a result, potentially saving several millions of dollars in exploration costs.’
DLR Outcome 4 - During the REF period, in Turkey, a Tertiary geological age has been established to be the key timing interval for gold mineralisation. The DLR has been critical in confirming or denying the age of gold-related mineralisation, which has as a result guided the company’s exploration programs where approximately CAD20million have been spent on exploration.
DLR Outcome 5 – Similarly during the REF period, in Greece, where the key geological ages are 33 to 23 and 23 to 5 million years ago, with the geological characteristics of each age of mineralisation being similar, the DLR has confirmed the timing of gold mineralization and directly guided the company’s exploration strategy that has a budget of up to CAD10million. The Chief Geoscientist, Eldorado Gold states: ‘We have used Re-Os dating of molybdenite on our prospects to determine which generation the mineralisation is related to, and the results have helped guide our exploration strategy in the region where we typically have an exploration budget of CAD5-10million.’
In summary, during the REF period, the outcome of DLR for several international mining companies working in several countries has provided critical data to strategically refine their exploration programs, and in one case revise the location of a principal mining site. Financially, this has permitted companies to maximise expenditure in terms of explorations that totals hundreds of USD and minimise environmental impact. Moreover, in the case of mine redevelopment, DLR has led to further security in terms of employment and country revenue.
5. Sources to corroborate the impact
Note that in general it is difficult to provide copies of internal technical documents / reports from mining companies who consider such material to be highly confidential, especially at the early exploration stages, and thus commercially very sensitive. We therefore provide testimony from industry end-users to corroborate impact of the Re-Os research.
[E1] Testimony: Principal Exploration Geologist, Minera Las Bambas, Av. El Derby 055 Torre 3 Piso 9, Santiago del Surco, Lima, Peru
[E2] Testimony: Principal Geologist, Rio Tinto, Rio Tinto Exploration, 1 Research Ave, Bundoora, Victoria, Australia
[E3] Testimony: Chief Geoscientist, Eldorado Gold Corporation, 550 Burrard Street, Vancouver, BC, Canada, V6C 2 B5
- Submitting institution
- University of Durham
- Unit of assessment
- 7 - Earth Systems and Environmental Sciences
- Summary impact type
- Technological
- Is this case study continued from a case study submitted in 2014?
- Yes
1. Summary of the impact
New data and understanding of fractured basement reservoirs developed at Durham in partnership with the hydrocarbon industry has materially underpinned the appraisal and drilling of the UK’s first basement-hosted oilfields (Clair, Lancaster and associated prospects) west of Shetland. With > 25 billion barrels of oil in place, the investments required and value of the potential hydrocarbon resources run into billions of US dollars and are of major strategic importance to the UK. Durham research has enabled other companies to explore UK basement assets and in 2020, directly influenced the chosen location of the forthcoming BP Clair Ridge basement well.
2. Underpinning research
Holdsworth & McCaffrey led a NERC Ocean Margins LINK (OML) project co-sponsored by BP, Statoil and CogNIT (2001-2005) investigating basement influences on fault and fracture development during North Atlantic rifting. New methodologies were developed to integrate fracture attribute datasets (e.g. geology, orientation, length, intensity, aperture, connectivity) collected at differing scales onshore with those interpreted using 3D seismic and well data from offshore areas. In 2004, a spin-out company, Geospatial Research Ltd (GRL) was set up (in part) to commercialise this methodology using NERC funding (Follow-on Fund), University seedcorn support and venture capital from the Regional Development Agency, OneNE.
Two key research findings from this project were:
Proof that the onshore-offshore methodology can address scaling issues between surface and subsurface datasets, improving understanding of the geometry, kinematics and fluid transport/storage potential of large-scale structures seen in cores and imaged on seismic reflection profiles [R1]. Attribute data extracted from the small-scale analogues (Virtual Outcrops) can be used directly to condition deterministic discrete fracture network (DFN) models [R2].
A demonstration that when pre-existing basement structures are oblique to far-field tectonic stresses, this leads to distinctive non-Andersonian, polymodal faulting patterns [R1].
In partnership with GRL, Holdsworth and McCaffrey further developed the knowledge and IP generated during the OML project. This included:
Fractured Reservoirs 3D Digital Atlas (2006-8), a Shell/BG, DTI-funded consortium using digital methods to construct deterministic 3-D fracture models in a range of tectonic and sedimentological environments [R2].
Four projects (including 3 PhDs) funded by the Clair Joint Venture Group (BP, Shell, ConocoPhillips, Chevron) and two projects with Hurricane Exploration (2006-present). These studied onshore analogues in Scotland (Lewisian Complex [R5, R6], Orcadian Basin **[R4]**) for fractured basement and cover reservoirs of the Rona Ridge, together with offshore core materials from the Clair, Lancaster, Halifax, Whirlwind and Lincoln basement fields. Durham onshore fracture characterisation work was integrated with structural interpretations made in the subsurface using offshore 3D seismic data, subsurface core logs and extensive thin sections from both cores and outcrops.
Three Statoil (Equinor)-funded onshore-offshore studies of faulting patterns and processes in the Faroe/Shetland Basin, including a PhD and PDRA [R3].
Research highlights derived from these projects demonstrating the fluid transport potential of fractured basement include:
The first detailed understanding of fault zone development and permeability evolution in upper crustal crystalline rocks [R3].
The first combined use of microstructural analysis and geochronology (Re-Os sulphide, U-Pb calcite) to determine the timing of fracture formation, mineralization and hydrocarbon filling in both an onshore analogue for the Clair Field [R4] and in offshore basement cores of the Rona Ridge [R5].
A new geological model for fractured basement plays where hydrocarbon influx is intimately associated with sediment ingress and low-temperature (50-150C) hydrothermal mineralization along open near surface (<2 km depth) seismogenic fissure systems [R5]. The fills act as natural proppants that hold fracture systems open over tens of millions of years. This allows the ingress and accumulation of oil in very large volumes (billions of barrels)
Demonstration that basement-hosted fracture systems are highly connected over at least 5 orders of magnitude length scale based on an analysis of the largest ever basement fracture attribute dataset collected anywhere in the world [R6].
3. References to the research
* = Holdsworth/McCaffrey research students; [number of citations, Web of Knowledge]
[R1] Wilson R.W.*, McCaffrey, K.J.W., Holdsworth R.E., Imber, J., Jones R.R., Welbon, A. & Roberts, D. 2006. Complex fault patterns, transtension and structural segmentation of the Lofoten Ridge, Norwegian margin: Using digital mapping to link onshore and offshore geology. Tectonics, 25, TC4018, http://doi.org/10.1029/2005TC001895 [34]
[R2] Jones, R.R., McCaffrey, K.J.W., Clegg, P.* Wilson, R.W.*, Holliman, N.S.,
Holdsworth, R.E., Imber, J., Waggott, S. 2009. Integration of regional to outcrop digital data: 3D visualisation of multi-scale geological models. Computers & Geosciences, 39, 4-18, https://doi.org/10.1016/j.cageo.2007.09.007 [90]
[R3] Walker, R.J.*, Holdsworth, R.E., Armitage, P.J. & Faulkner, D.R. 2013. Fault zone permeability structure evolution in basalts. GEOLOGY, 41, 59-62, https://doi.org/10.1130/G33508.1 [27]
[R4] Dichiarante, A.M.*, Holdsworth, R.E., Dempsey, E., Selby, D., McCaffrey, K.J.W., Michie, U. McL., Morgan, G. & Bonniface, J. 2016. New structural and Re–Os geochronological evidence constraining the age of faulting and associated mineralization in the Devonian Orcadian Basin, Scotland. Journal of the Geological Society, http://doi.org/10.1144/jgs2015-118 [11]
[R5] Holdsworth, R.E., McCaffrey, K.J.W., Dempsey, E., Roberts, N.M.W., Hardman, K., Morton, A., Feely, M., Hunt, J., Conway, A. & Robertson, A. 2019. Natural fracture propping and earthquake-induced oil migration in fractured basement reservoirs. Geology, 47, 700-704, http://doi.org/10.1130/G46280.1 [11]
[R6] McCaffrey, K.J.W., Holdsworth, R.E., Pless, J.*, Franklin, B.S.G.* and Hardman, K.* 2020. Basement reservoir plumbing: fracture aperture, length and topology analysis of the Lewisian Complex, NW Scotland. Journal of the Geological Society, https://doi.org/10.1144/jgs2019-143 [4]
Paper [R1] was entered as research output for RAE 2008. 97.3% of the Durham UoA 17 Research outputs were rated ≥ 2*, with 71.2% rated ≥ 3*.
Papers [R2] and [R3] are highly cited. Paper [R3] was entered as a research output for REF 2014. 100% of the Durham UoA 7 Research outputs were rated ≥ 2*, with 88% rated ≥ 3*.
Papers [R4-6] are all related to the research that underpins the impact related to the Rona Ridge hydrocarbon fields. Paper [R5] is an output submitted for REF 2021.
A similar ICS was a finalist and runner up in the NERC Impact Awards 2018 competition [E9].
*Grants (awarded to Holdsworth & McCaffrey unless indicated otherwise; linked to **[Research]*):
NERC OML project: ‘Quantifying fault zone evolution and basement reactivation in passive margins.’ (NER/T/S/2000/01018) | GBP237,000 | 2002-5 [R1, R2, R5, R6] |
---|---|---|
NERC Follow-on Fund: ‘The commercialisation of GAVA - Geospatial Acquisition, Visualisation and Analysis: a new tool for field-based scientists. (NE/C506964/1) [Led to creation of GRL] | GBP87,000 | 2004-6 [R2] |
Royal Society Industrial Fellowship to McCaffrey | GBP91,000 | 2005-9 |
BP postdoc to Wilson | GBP100,000 | 2006-7 [R1] |
NERC CASE studentships (Watts, Moy, Ashby) | ca GBP200,000 | 1998-2010 |
Statoil PhD student, Faroes fracture systems To Holdsworth & Imber | GBP100,000 | 2006-9 [R3] |
ITF JIP ‘FRE3DA’ (Shell, BG, DTI) postdoc (Wightman) | GBP120,000 | 2006-8 [R2] |
Statoil postdoc (Walker): fractures in basalts | GBP250,000 | 2009-10 [R3] |
NStar Proof of Concept Funding (to GRL) | GBP60,000 | Loan repaid |
NERC KE Fellowship to Holdsworth: ‘Development of opportunities for co-financed research with industry, and Knowledge Networks/Clubs within area of hazard and Risk, and Energy.’ 1 Oct 2010 - 30 Sep 2012. | GBP145,000 | 2009-12 |
Clair JVG PhDs (Pless, Franklin, Dichiarante) | GBP330,000 | 2007-2015 [R4-6] |
Clair JVG Re-Os dating study (Selby & Holdsworth) | GBP220,000 | 2013-2015 [R4] |
BP/Clair JVG Clair Ridge study | GBP83,060 | 2014-2016 [R5-6] |
Hurricane Exploration: Fractured basement of the southern Rona Ridge | GBP47,862 | 2018-2020 [R5] |
Since 2000, Holdsworth (h index 44), McCaffrey (h index 30) have published over 200 papers on fault reactivation and fractured basement reservoirs studying examples from UK, Europe, S America, N America, Greenland, Japan and the Philippines. Awards for research by Holdsworth include a Geological Society of America Fellowship (2004) and the Lyell Fund (2000), Aberconway Medal (2006) and Coke Medal (2018) from the Geological Society, London (GSL). The Aberconway Medal is awarded for “distinction in the practice of geology, with special reference to work in industry.” Other awards for research include the GSL Murchison Fund (to McCaffrey 2005); the Clough Medal (to Holdsworth 2018) and Clough Memorial Award (to former staff member Imber 2003) by the Edinburgh Geological Society; 2 Royal Society Industry Fellowships (McCaffrey 2006, Imber 2012) and a NERC Knowledge Exchange Fellowship (Holdsworth 2009).
4. Details of the impact
Fractured basement reservoirs are a globally underexploited hydrocarbon resource, with only 126 commercially producing fields spread across 26 countries [R5]. The crystalline nature of the low porosity basement means that almost all the hydrocarbon is held in fracture systems. These plays are poorly understood by industry and are difficult to explore due to problems with geophysical imaging in basement rocks and a paucity of core samples core [E1-6].
Holdsworth & McCaffrey’s research findings and expertise have had impacts for the appraisal and development of the UK’s first ever basement-hosted oil fields along the Rona Ridge, west of Shetland (see below). The investments required and value of the potential hydrocarbon resources run into billions of US dollars and are of major strategic importance to the UK [E1-3, E6]. They include:
The giant Clair oilfield is operated by BP for the Clair Joint Venture Group (CJVG; a consortium of BP, Shell, ConocoPhillips [now Chrysaor] and Chevron). The field is the largest hydrocarbon resource in the UK Continental Shelf with an estimated 7 billion barrels of Stock Tank oil initially in place (STOIIP) [E1, E2]. The Phase I area came on stream in 2005, whilst the Clair Ridge (Phase II) began production in 2019. The reservoir target is Devonian sandstones that rest directly on Lewisian-like metamorphic basement. Both rock units host oil and are highly faulted, with fracture description and water flood performance considered to be the two main risks in field development. A dedicated basement well in the Clair Ridge is also due to be drilled in 2021 [E2].
In 2009 Hurricane Exploration Ltd drilled and tested the UK’s first exploration well targeted specifically at fractured basement. Two further appraisal wells and two horizontal development wells were then drilled and led to the UK Oil and Gas Authority (OGA) assigning field status to Lancaster in 2015. The Lancaster field (2.3 billion barrels STOIIP) produced its first oil in June 2019 from two wells at a rate of 20,000 barrels of oil per day. Hurricane has also undertaken further basement exploration making additional discoveries at its Whirlwind, Lincoln and Halifax prospects (estimated 15.8 billion barrels) all of which lie along the Rona Ridge [E3, E6].
In 2018, Spark Petroleum acquired the licence to develop the Bader prospect located in the region separating Clair from the Hurricane fields.
The Durham research that has that has impacted on the developments outlined above stems from analysis of the fault and fracture systems in the sub-surface Rona Ridge (using core samples, well data and geophysical images) and from surface analogues of the equivalent fractured basement (Lewisian Complex) and cover sequences (Orcadian Basin) in NW Scotland [E1-3, E7-8].
For the CJVG, the Clair Reservoir Development Manager [E1] stated in 2018 that the Durham research set out in our final report [E7] has “significantly improved the industry understanding of the basement rock hydrocarbon prospectivity and potential” and that it “gave sufficient confidence to the JV to allow advance planning of a dedicated basement well which will be produced through the Clair Phase I facility (cost GBP22 million)”. They also highlighted that this work helped demonstrate the CJVG commitment to developing basement resources and that Durham “helped the basement licence retention negotiation with OGA” during 2018. In 2020, the Clair Area Reservoir Development Manager [E2] explained that, in the planning of the dedicated basement well (costing GBP20-25 million), the views of the Durham team were “instrumental in convincing the Clair JV that a crestal well location is a better option, with a higher flow-rate potential than the previous well location. The revised well location is a shorter well, implying a cost saving in the range of GBP1-5 million.”
For Hurricane, the CEO has written that two reports on fractured basement commissioned from Durham in 2007 **[E8] (**precursors to **[R5-6]**) were “ a big influence on our decision to explore and ultimately develop fields in the southern part of the Rona Ridge west of Shetland” [E3]. He has also stated that since 2013, “ Durham onshore data and expertise on fractured basement rocks has been used by Hurricane in reducing uncertainties by constraining its subsurface models which are utilised for determining drilling locations and quantifying the likely economic returns in terms of hydrocarbon production and resource of the Lancaster field”. Since each development well costs upwards of GBP20 million and the decision to finally sanction the entire development programme is significant in both financial and economic terms [E1-3, E5, E6]. In summing up, the CEO states that research at Durham was: “pivotal in allowing us to develop Lancaster as the first fractured basement reservoir ever established in the UKCS region.”
Since 2013, Holdsworth has additionally led annual field workshops with CJVG geoscientists (42 individuals to date) to view fractured analogues in N Scotland. This has helped the industry subsurface teams to better conceptualise the structural framework in the fractured basement and associated Devonian cover sequences and to design improved alternative fracture models [E1-3, E5]. A similar field workshop was run for Hurricane in 2012 and influenced their conceptual models for the Lancaster and other fields in the period 2014-present [E3].
A similar Case Study was a finalist and runner up in the NERC Impact Awards 2018 competition in the Economic Impact category [E9]. Award money from this success was used to host a stakeholder workshop on “ The Geology of Fractured Basement Reservoirs” held in the Outer Hebrides in September 2019 and attended by representatives from 13 companies and the UK Oil & Gas Authority (OGA). A day of presentations and discussion was followed by 2 days in the field visiting onshore analogues of fractured basement rocks. Impacts derived from that event are presently on hold due to effects of the COVID pandemic.
5. Sources to corroborate the impact
E1 - Testimony from Clair Subsurface Manager, BP (letter 28th March 2018)*
E2 – Testimony from Clair Area Reservoir Development Manager, BP (letter May 2020)*
E3 – Testimony from CEO Hurricane (letter 6th February 2020)*
E4 – Testimony from Global Chief Scientist, Energy & Geoscience Institute at the University of Utah [formerly VP, Statoil/Equinor] (letter 23rd February 2020)*
E5 – Testimony from Andy Conway, OGA [formerly Conocophillips] (letter 16th February 2020)*
E6 – RPS Competent Person's Reports for Lancaster Field (2017) and for ‘West of Shetland Assets’ (Lincoln, Whirlwind, Halifax, Strathmore) (2017).*
E7 – CONFIDENTIAL: Holdsworth R.E. & McCaffrey, K.J.W. 2016. Understanding the Clair field basement and its associated fracture systems: implications for reservoir appraisal. Final report for the Clair JVG, 315pp.*
E8 – CONFIDENTIAL: Consultancy reports commissioned by Hurricane Exploration plc. i) Holdsworth, R.E. et al. 2007. Outcrop Data as an Analogue to HEX Lewisian Basement Acreage: Characterisation of Lewisian Fracturing in Scotland & the Møre-Trøndelag Fault Zone in Norway. Consultancy Report commissioned by Hurricane Exploration plc. ii) Jones, R. et al. 2007. Outcrop Data as an Analogue to HEX Lewisian Basement Acreage: Analysis of Fracturing on Lewis & Harris, Outer Hebrides.*
E9 – Documents related to 2018 NERC Impact Award (Economic category), including certificate and NERC press releases & movie.*
- Submitting institution
- University of Durham
- Unit of assessment
- 7 - Earth Systems and Environmental Sciences
- Summary impact type
- Societal
- Is this case study continued from a case study submitted in 2014?
- No
1. Summary of the impact
Communities living near active volcanoes, and the agencies protecting them, require evidence-based advice on how to best reduce exposure to volcanic emissions, in order to prevent respiratory symptoms and diseases. This case study documents how research, led by Horwell, has generated critical evidence and protocols which have enabled both global and community-specific advice to be produced. The evidence has been incorporated into World Health Organization (in the Americas; Pan American Health Organization, PAHO) guidelines and has directly led to changes in policy and practice in several volcanic eruptions since 2017, with agencies providing communities with effective respiratory protection in Indonesia, Hawaii and Guatemala.
2. Underpinning research
Over the past decade a variety of research projects, led by Horwell, have been conducted at Durham University with the aim of enabling community protection from potentially harmful volcanic emissions. When volcanic ash falls on a community, the questions that are immediately asked by both the public and disaster management and health agencies are ‘Is it harmful to breathe this air?’ and ‘How can I protect myself?’. Medical studies (e.g., epidemiology or clinical studies) may take months or even decades, to assess if the emissions are harmful so Horwell developed rapid techniques and protocols for physicochemical analysis of ash, enabling swift health hazard assessment. Laboratory experiments and social surveys have also been conducted to build the first evidence base on the effectiveness of various forms of respiratory protection for community protection.
Since 2007, Horwell and her group have developed a range of physicochemical techniques for rapidly assessing the respiratory-health-pertinent characteristics of volcanic ash, to enable decision making on the need for exposure reduction during volcanic crises. Following testing and publication of the underpinning techniques [e.g. R1], a rapid analysis protocol was developed and published on the International Volcanic Health Hazard Network (IVHHN)* website. The protocol was then applied in three eruptions [e.g. R2] and tested in other non-crisis situations. The protocol has four stages: I) sample collection; II) particle size analysis (a critical step, because if ash is too coarse to enter the lung then it cannot be a respiratory hazard); III) full characterisation of health-pertinent physicochemical properties; IV) reporting. Agencies can decide on whether to enact the full or partial protocol, depending on the scale of the eruption and how fine-grained the ash is.
The Health Interventions in Volcanic Eruptions (HIVE; Horwell was PI) consortium project built the first evidence base on effective respiratory protection for community use, for exposure reduction against volcanic ash. Laboratory studies were conducted, at the Institute of Occupational Medicine, Edinburgh, on 17 different forms of respiratory protection (RP) used by communities during eruptions around the world. The RP ranged from handkerchiefs, shawls and hijab to facemasks including surgical masks and industry-certified devices (e.g. N95 masks). The RP were tested for their filtration efficiency (FE) and their ‘leakage’ – a combined measure of both fit and filtration, tested on human volunteers [R3]. The results showed that the best type of RP, in terms of both FE and fit, was the N95 mask. Around the world, surgical masks are commonly distributed by agencies but, whilst the results showed that these had excellent filtration, they did not fit well, unless an extra layer of cloth was added to hold the mask better to the face [R3], which the lab volunteers, and community testers in Indonesia, found uncomfortable. All of the tested cloth materials performed poorly against volcanic ash. Folding cloth into multiple layers improved its FE, but multi-layered facemasks, such as surgical masks, were more effective. Many agencies recommend wetting cloth materials or surgical masks, but the experiments did not find any additional protective benefits to wetting. An ethical framework was also developed to aid agency decision making on which types of RP to recommend [R4]. The social research showed that different cultures have different perceptions of the health risk from volcanic ash, and the need to protect themselves, so advice must be tailored to fit the needs of individual communities [e.g. R5].
In 2015, Horwell worked with communities (by conducting focus group discussions and questionnaire surveys) to understand how they protect themselves from the impacts of the constant gaseous emissions (known as ‘vog’) from Kīlauea volcano, Hawaii and how this relates to official guidance given by federal and state agencies. The research found that, whilst it was difficult for many people to reduce exposure to vog, given their outdoor lifestyles, the tropical climate and, hence, lack of robustness of housing design, the communities had developed a range of strategies for coping with the symptoms which they attribute to the vog [R6]. The work resulted in the formation of an interagency (GO) partnership to revise the existing public health advice, based on the study.
3. References to the research
Number after each URL is journal 5-yr impact factor
R1. Horwell C.J., Fenoglio. I., Fubini. B. 2007. Iron-induced hydroxyl radical generation from basaltic volcanic ash. Earth and Planetary Science Letters. 261, 662-669. https://www.sciencedirect.com/science/article/pii/S0012821X07004888?via%3Dihub. 5.273
R2. Horwell, C.J., Baxter, P.J., Hillman, S.E., et al. 2013. Physicochemical and toxicological profiling of ash from the 2010 and 2011 eruptions of Eyjafjallajökull and Grímsvötn volcanoes, Iceland using a rapid respiratory hazard assessment protocol. Environmental Research, 127, 63-73. https://www.sciencedirect.com/science/article/pii/S0013935113001539. 5.715
R3. Steinle, S., Sleeuwenhoek, A., Mueller, W., Horwell, C.J., et al. 2018. The effectiveness of respiratory protection worn by communities to protect from volcanic ash inhalation; Part II: Total inward leakage. International Journal of Hygiene and Environmental Health 221(6): 977-984. https://www.sciencedirect.com/science/article/pii/S1438463917308027 5.081
R4. McDonald, F., Horwell, C.J., Wecker, R., et al. 2020. Facemask use for community protection from air pollution disasters: An ethical overview and framework to guide agency decision making. International Journal of Disaster Risk Reduction 43: 101376. https://www.sciencedirect.com/science/article/pii/S2212420919308295 3.275
R5. Covey, J.A., Horwell, C.J., Rachmawati, L., Ogawa, R., Martin del Pozzo, A.-L., Armienta, M.A., Nugroho, F. and Dominelli, L., 2019. Factors motivating the use of respiratory protection against volcanic ashfall: A comparative analysis of communities in Japan, Indonesia and Mexico. International Journal of Disaster Risk Reduction, 35: 101066. https://www.sciencedirect.com/science/article/pii/S2212420918313670 3.275
R6. Horwell, C.J. Community perceptions of volcanic gas exposure, protection and advice on Hawai’i island: a first assessment. Executive Summary and Report submitted to Hawaii Agencies (Department of Health, Civil Defence, National Park Service, US Geological Survey). December 2015.
Horwell is regarded as a leading publisher of research on volcanoes and health. She was awarded the European Geosciences Union’s 2020 Plinius medal for interdisciplinary research on natural hazards and is currently the President and founding leader of the American Geophysical Union’s GeoHealth Section. She has 59 papers published in high impact factor international journals across the environmental, health, volcanology, toxicology, social and humanitarian research disciplines. *Horwell is also Director of the International Volcanic Health Hazard Network ( www.ivhhn.org) which is the international umbrella organisation for research and public dissemination of information about health issues related to eruptions.
Wellcome Trust & DfID Consortium Grant. ‘A new evidence base for respiratory Health Interventions in Volcanic Eruption crises’ (HIVE). Horwell, C.J. (P.I.) Awarded through Elrha’s Research for Health in Humanitarian Crises Programme. GBP611,710. 11/15-03/19. http://community.dur.ac.uk/hive.consortium/
British Council Researcher Links grant: ‘Health interventions and messaging downwind of Kilauea volcano, Hawaii’. Horwell, C.J. (P.I.) GBP9,604. 03/14-03/15.
NERC Urgency Grant. ‘Rapid assessment of the potential health hazard of ash from Eyjafjallajökull volcano, Iceland’ Horwell, C.J. (P.I.) GBP37,689. 07/10-03/11.
4. Details of the impact
Horwell’s research, to build an evidence base on the respiratory health hazards of volcanic emissions and effective methods of community protection, has resulted in incorporation of methodological protocols into country-level emergency management plans, co-development of informational products with communities and agencies, and their uptake and use during volcanic crises. This has resulted in raised awareness of effective actions in communities and changes in policy and practice related to mask distribution by agencies.
When a volcano erupts, agencies (usually GOs and NGOs with public health, civil protection, disaster management and humanitarian remits) will often distribute facemasks to reduce individual exposures to volcanic emissions, hence reducing the risk of harm from ash inhalation. Until recently, distributed facemasks have usually been those that have already been stockpiled for public health emergencies (e.g., surgical masks stored for influenza pandemics). Until the HIVE project, there was little-to-no evidence of the effectiveness of these masks in community settings for volcanic crises.
The Pan American Health Organization (PAHO) which is the World Health Organization’s (WHO) Regional Office for the Americas, has rewritten its guidelines on the health impacts of volcanic eruptions. Within those guidelines, information related to respiratory protection is based on the evidence provided by the HIVE research [E1]. These guidelines replace the current information available across the WHO, globally. The HIVE findings and impact were also summarised in a special supplement of PAHO’s Disasters Newsletter (October 2020), which reaches approximately 27,000 experts worldwide [E1], enabling awareness raising at a local level and, hence, faster implementation of the guidance during volcanic emergencies. A new IVHHN/HIVE standardised epidemiological protocol, for use in eruption crises, was also incorporated as part of PAHO’s Regional Response Team assessment tools. Dr Ciro Ugarte, Director of Health Emergencies at PAHO, has said: “The contribution of the HIVE project has been instrumental in building and sharing scientific evidence on respiratory protection from volcanic ash within the Americas. I would like to specially recognise Durham University for this essential collaboration towards a more resilient health sector in the Americas.” [E1]
In late 2017, the Mt Agung, Bali volcanic crisis triggered a critical shift in the approach to community protection in volcanic emergencies in low-to-middle income countries (LMICs). The fundamental difference between the preparedness for the Agung eruption, and that of previous volcanic crises in LMICs, came from a combination of changes in humanitarian practice, such as the advent of crowdfunding platforms, greater coordination of grassroots response, and a sudden move away from the precautionary principle (any intervention is better than no intervention) towards the principles of effectiveness (only providing proven interventions) and social justice (equality in public health provision). This ethical decision-making was based on the results of the HIVE project [R3-5], which showed that industry-certified (N95) masks were the most effective at protecting against ash inhalation [E2]. This resulted in the donation, stockpiling and distribution of 75,000 N95 masks in Bali by a consortium of NGOs known as Mt Agung Relief (led by Kopernik), a situation which has not previously been observed in a volcanic crisis in a LMIC (see [E1] for case study). Mt Agung Relief also produced a series of public informational products on ash protection based on the findings of the HIVE project [E2-3]. Horwell also shared the findings of the HIVE project through social media and engaged in discussions with communities in Bali through local Facebook groups such as Community Ubud, resulting in evidence-based community-level decision making [E3].
The results of the HIVE research [R3-5] have subsequently been incorporated into new public information products (printable and audio-visual), downloadable from the IVHHN website. They were co-developed with Indonesian NGOs, GOs and community representatives and are now available in English, Spanish, Indonesian, Filipino, Japanese and Turkish. The English and Spanish printable products (booklet, poster and leaflet) are endorsed by PAHO/WHO and carry their logos [E1]. These products provide information on how to protect from inhaling ash (2,443 video views 09/20) and how to fit a facemask (9,946 video views 09/20). Another video documents people’s experiences of protection during the 2010 Merapi (Indonesia eruption), to help people prepare for future eruption crises (9,618 video views 09/20). During the 2018 ash eruptions of Kīlauea volcano, Hawaii, a major PPE manufacturer donated over 100,000 N95 particulate respirators, in collaboration with local NGOs and GOs, a decision informed by the HIVE evidence [E4]. Local guidance was also developed by the Hawaii Department of Health (HDOH), based on the IVHHN products [E4]. Additionally, several NGOs in Indonesia have used the information to make their own products, for example, the Yakkum Emergency Unit has produced a series of posters [E5]. The Indonesian Red Cross (PMI) and Direct Relief (a US based humanitarian relief organization) have said that they will be printing and distributing the products in future eruption crises [E6; E7].
In January 2019, the HIVE project team returned to Indonesia to conduct four train-the-trainer workshops, on how to fit a facemask, for more than 70 representatives of local agencies and health centres, with the International Society for Respiratory Protection and the Indonesian Red Cross. Those representatives are now engaged in further training and, so far, at least 800 people have received this training [E6].
In Hawaii, the research finding [R6] that communities were coping with vog (gas) exposure in different ways from the official advice, and that the advice was viewed by some as inappropriate given their lifestyles, triggered a complete rewrite of that advice by the HDOH, US Geological Survey (USGS) and IVHHN (Horwell) [E4]. The research also showed how existing advice offered by different agencies varied on different websites. Through workshops held as part of the research, a new Interagency (GO) Partnership was formed (HDOH, Civil Defense, USGS, US National Park Service, County of Hawaii etc.) and an agreement was made that all future advice on vog protection would be consistent across the different agencies. The new guidelines have been published as a booklet, rack brochure and poster, and are available online on a new, comprehensive ‘web dashboard’ which Horwell co-designed with the interagency partnership. The Vog Dashboard ( https://vog.ivhhn.org/), is hosted by IVHHN so that no particular Hawaii/ US agency appears to lead the Partnership and all vog information and data can be accessed from one portal. The guidelines were written to be more reflective of Hawaiian lifestyles and to incorporate the communities’ strategies for coping, where these were evidence based. The agencies then removed their old advice from their own websites so that there was a single point of information [E8]. In May 2018, an unprecedented volcanic crisis emerged as the Kīlauea eruption changed location and style, resulting in multiple volcanic hazards and impacts within the community. The Vog Dashboard became a key source of official information, receiving approximately 50,000 visits per week during this crisis and was also highly recommended by various international media outlets [E9]. Fenix Grange, HDOH, said: “We are indebted to Dr. Horwell and IVHHN for the extraordinary, accessible technical resources and the expertise provided. Their contributions to the massive, multi-disciplinary response to the volcanic eruption crisis of 2018 (and prior events) were very important to the mission of HDOH to protect the people of Hawaii” [E4].
The ash analysis protocols, adopted by IVHHN, have been incorporated into New Zealand governmental policy to be enacted in any future eruptions [E10]. This coordinated framework for public health response to eruptions involves governmental ministries, the national geological survey (GNS Science), Regional Councils, the Met Service and universities. When an eruption occurs, the framework of responses will be enacted and ash collection and characterisation, in accordance with the IVHHN protocols, is part of that crisis management plan. Therefore, official guidelines and practice have been established which purposefully incorporate Horwell’s protocols. Horwell was invited to New Zealand, in Nov. 2013, to present her research to the governmental ministries and at a forum of regional public health representatives, which kicked off the process of writing and establishing the framework.
In 2017, key organisers of the framework (at GNS Science and Massey University) advised on crisis response for an eruption in Vanuatu. They enacted the IVHHN protocol, as part of that response [E10]. Parts of the IVHHN protocol have also been applied in other volcanic crises by local agencies around the world. “Claire’s work has led to improved capacity for rapid eruption response in both NZ and Vanuatu, including the activities of Civil Defence and Emergency Management Groups throughout the North Island.” Graham Leonard, GNS [E10].
To conclude, Horwell’s research on how to protect communities from exposure to volcanic emissions has influenced policy and practice in numerous health-facing organisations, around the globe, resulting in better preparedness, improved public health advice and protection, and enhanced understanding of the hazards of volcanic ash.
5. Sources to corroborate the impact
[E1] PAHO-WHO evidence compilation: testimonial letter, Disasters Supplement (https://www.paho.org/disasters/newsletter/index.php?lang=en\), webpage
[E2] Kopernik testimonial letter
[E3] Agung eruption evidence compilation
[E4] Hawaii Department of Health and United States Geology Survey testimonial letters 2016-2019
[E5] Yakkum Emergency Unit poster
[E6] Indonesian Red Cross (PMI) testimonial letter
[E7] Direct Relief testimonial letter
[E8] Hawaii agencies advice change, evidence compilation (screen grabs)
[E9] International media links mentioning the Vog dashboard/IVHHN during the Kilauea crisis
[E10] New Zealand GNS Science testimonial letter