Assessment of MgZr4P6O24 as a Solid Electrolyte for Sensing Mg in Molten Non-Ferrous Alloys
- Submitting institution
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The University of Leeds
- Unit of assessment
- 12 - Engineering
- Output identifier
- CHEM-112
- Type
- D - Journal article
- DOI
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10.1149/1945-7111/ab6556
- Title of journal
- Journal of the Electrochemical Society
- Article number
- 027532
- First page
- -
- Volume
- 167
- Issue
- 2
- ISSN
- 0013-4651
- Open access status
- Compliant
- Month of publication
- January
- Year of publication
- 2020
- URL
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- Supplementary information
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- Request cross-referral to
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- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
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2
- Research group(s)
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-
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- Mg-ion conductors are important for developing Mg-batteries, potentiometric gas sensors and Mg-sensors for in-line process control and monitoring of alloying/casting/recycling operations in non-ferrous metallurgical industries, leading to significant cost and energy savings. Building on preliminary 2016 work describing the sol-gel synthesis of a new family of inorganic solid electrolytes which undergo solid-state phase transformation between 1173-1273K (pubs.acs.org/doi/10.1021/acs.jpcc.6b05036), this work developed and tested sensing capabilities of the material forming the basis for a successful KTP (Innovate UK-KTP008993) proposal with Rautomead Ltd to produce a sensor for measuring Mg in molten metals that integrates with the process control system during continuous casting.
- Author contribution statement
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- Non-English
- No
- English abstract
- -