Local Platinum Environments in a Solid Analogue of the Molecular Periana Catalyst
- Submitting institution
-
Queen Mary University of London
- Unit of assessment
- 12 - Engineering
- Output identifier
- 2581
- Type
- D - Journal article
- DOI
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10.1021/acscatal.5b02305
- Title of journal
- ACS Catalysis
- Article number
- -
- First page
- 2332
- Volume
- 6
- Issue
- 4
- ISSN
- 2155-5435
- Open access status
- Out of scope for open access requirements
- Month of publication
- March
- Year of publication
- 2016
- URL
-
-
- Supplementary information
-
-
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
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12
- Research group(s)
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-
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- We have identified the local compositions, and structures of platinum species incorporated into covalent triazine framework materials, a solid analogue of the molecular Periana catalyst for methane oxidation to methanol. Using a combination of solid-state 195Pt nuclear magnetic resonance spectroscopy, aberration-corrected scanning transmission electron microscopy, X-ray photoelectron spectroscopy and X-ray absorption spectroscopy, we have determined important similarities and differences between the Pt-CTF and Periana catalysts. This study revealed novel pathways towards better catalysts design for methane oxidation. This is an interdisciplinary work with Max-Planck Institute for Carbon Research and Oakridge National Lab in USA
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -