Stopping Hydrogen Migration in its Tracks: The First Successful Synthesis of Group Ten Scorpionate Complexes Based on Azaindole Scaffolds
- Submitting institution
-
University of South Wales / Prifysgol De Cymru
- Unit of assessment
- 12 - Engineering
- Output identifier
- 3435106
- Type
- D - Journal article
- DOI
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10.1021/acs.inorgchem.8b02456
- Title of journal
- Inorganic Chemistry
- Article number
- -
- First page
- 359
- Volume
- 58
- Issue
- 1
- ISSN
- 0020-1669
- Open access status
- Compliant
- Month of publication
- January
- Year of publication
- 2019
- URL
-
-
- Supplementary information
-
-
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
-
6
- Research group(s)
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A - Sustainable Environment Research Centre
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- This article provides a greater level of understanding on the mobility of hydrogen atoms within transition metal complexes and will directly impact on the future design of transition metal-based materials able to generate and store molecular hydrogen for energy applications. This is important since the vast majority of industrial relevant catalytic transformations involve these migrations. This Leverhulme Trust funded research (RPG-2015-097) explores a system in which hydrogen migration is stopped, allowing a degree of control over this process. This will benefit industry by lowering the cost and improving efficiency across a broad range of industrially relevant reactions.
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -
