Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen.
- Submitting institution
-
University of Oxford
- Unit of assessment
- 12 - Engineering
- Output identifier
- 9541
- Type
- D - Journal article
- DOI
-
10.1038/nchem.2471
- Title of journal
- Nature chemistry
- Article number
- -
- First page
- 684
- Volume
- 8
- Issue
- 7
- ISSN
- 1755-4330
- Open access status
- Out of scope for open access requirements
- Month of publication
- March
- Year of publication
- 2016
- URL
-
-
- Supplementary information
-
https://static-content.springer.com/esm/art%3A10.1038%2Fnchem.2471/MediaObjects/41557_2016_BFnchem2471_MOESM150_ESM.pdf
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
-
10
- Research group(s)
-
-
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- This paper provides the first direct proof that lithium-rich 3d transition metal oxides can also store charge on the oxide ions in addition to the metal ions. Experimental evidence showing that ionic metal-oxygen interactions are critical in promoting oxygen redox is also presented, providing design rules for the future discovery of new materials. It has led to new collaborations with groups at Diamond, Bath and Liverpool, and a major new grant from the Faraday Insitution on high capacity cathodes (FIRG016).
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -