Selectivity in the gas-phase hydrogenation of 4-nitrobenzaldehyde over supported Au catalysts
- Submitting institution
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The University of Lancaster
- Unit of assessment
- 12 - Engineering
- Output identifier
- 280602590
- Type
- D - Journal article
- DOI
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10.1016/j.jcat.2013.10.011
- Title of journal
- Journal of Catalysis
- Article number
- -
- First page
- 333
- Volume
- 309
- Issue
- -
- ISSN
- 0021-9517
- Open access status
- Out of scope for open access requirements
- Month of publication
- January
- Year of publication
- 2014
- URL
-
-
- Supplementary information
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-
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
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4
- Research group(s)
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-
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- An outcome of collaboration between the UK catalysis engineering team and the French surface science team from UPMC Univ Paris 06 and CNRS-UMR 7197. The work combines thermodynamic analysis, surface characterisation and kinetic measurements to establish a method of designing gold catalysts for the selective reduction of EITHER the carbonyl OR nitro group in nitrobenzaldehyde. The design principles are extendable to other syntheses where multiple reactive functionalities are present, leading to an invited book chapter (RSC Catalysis Series No.18: Heterogeneous Gold Catalysts and Catalysis, 2014, 424) and promoting gold catalyst use in other areas (e.g., electrocatalysis, Nanoscale, 2020, 12, 4314).
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -
