A Fluctuation Equation of State for Prediction of High-Pressure Densities of Ionic Liquids
- Submitting institution
-
Queen's University of Belfast
- Unit of assessment
- 12 - Engineering
- Output identifier
- 199648529
- Type
- D - Journal article
- DOI
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10.1038/s41598-017-06225-9
- Title of journal
- Scientific Reports
- Article number
- 5563
- First page
- -
- Volume
- 7
- Issue
- -
- ISSN
- 2045-2322
- Open access status
- Compliant
- Month of publication
- July
- Year of publication
- 2017
- URL
-
-
- Supplementary information
-
-
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
-
4
- Research group(s)
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D - Chemical
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- This paper presents the prediction of volumetric properties of liquids as a function of temperature and pressure using a dedicated Equation of State and thereby for the first time demonstrated its applicability for very dense fluids as ionic liquids. To date, this approach is recognized as the best model to predict density, molar volume and mechanical properties of a large set of liquids up to their critical point within the sole knowledge of their atmospheric data like density and isothermal compressibility which can be both determined easily using commercial apparatuses (i.e. densimeter and speed of sound meter).
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -