Crowding out: ligand modifications and their structure directing effects on brucite-like {Mx(μ3-OH)y} (M = Co(ii), Ni(ii)) core growth within polymetallic cages
- Submitting institution
-
University of Wolverhampton
- Unit of assessment
- 12 - Engineering
- Output identifier
- 1634
- Type
- D - Journal article
- DOI
-
10.1039/c8dt04229b
- Title of journal
- Dalton Transactions
- Article number
- -
- First page
- 1477
- Volume
- 48
- Issue
- 4
- ISSN
- 1477-9226
- Open access status
- Technical exception
- Month of publication
- December
- Year of publication
- 2018
- URL
-
-
- Supplementary information
-
http://www.rsc.org/suppdata/c8/dt/c8dt04229b/c8dt04229b1.pdf
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
-
10
- Research group(s)
-
-
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- Many of the complexes in this work exhibit brucite like Mx(OH)y (M = Ni(II), Co(II)) inorganic cores and therefore have more than a passing resemblance to the types of Cobalt hydroxide /phosphate (Co-OEC) and nickel hydroxide /phosphate (Ni-OEC) electrocatalysts employed in the splitting of water (giving H2 and O2 and represents a viable future sources of energy). Indeed, Nocera and co-workers at Harvard have used one of our previously reported analogous [Co(II)7] and [Co(III)Co(II)6] complexes to model their water splitting by analysing the mechanism of cobalt self-exchange electron transfer .
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -