A facile synthetic route to a family of Mn<sup>III</sup>monomers and their structural, magnetic and spectroscopic studies
- Submitting institution
-
University of Wolverhampton
- Unit of assessment
- 12 - Engineering
- Output identifier
- 1633
- Type
- D - Journal article
- DOI
-
10.1002/ejic.201601124
- Title of journal
- European Journal of Inorganic Chemistry
- Article number
- -
- First page
- 5123
- Volume
- 2016
- Issue
- 32
- ISSN
- 1434-1948
- Open access status
- Technical exception
- Month of publication
- October
- Year of publication
- 2016
- URL
-
-
- Supplementary information
-
https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fejic.201601124&file=ejic201601124-sup-0001-SupMat.pdf
- Request cross-referral to
- -
- Output has been delayed by COVID-19
- No
- COVID-19 affected output statement
- -
- Forensic science
- No
- Criminology
- No
- Interdisciplinary
- No
- Number of additional authors
-
8
- Research group(s)
-
-
- Proposed double-weighted
- No
- Reserve for an output with double weighting
- No
- Additional information
- This paper details a quick and easy synthetic route to Mn(III)F3(L) complexes that we have shown to possess significant magnetic anisotropy. These can be used as precursors in the production of Single-molecule magnets (discrete magnetic materials with potential applications in information storage, quantum computing and as magnetic coolant materials). More recently, we have employed these Mn(III)F3(L) complexes as oxidative catalysts and initial results are promising as they have been shown to successfully epoxidise trans-stilbene and the sulfoxidation of 4-nitrothioanisole and 4-nitrophenyl phenyl sulphide.
- Author contribution statement
- -
- Non-English
- No
- English abstract
- -